![]() It is well-known that, before the solute molecules can self-assemble to form crystals, they must leave their solvation shell. Thermodynamically, the antisolvent is known to increase the chemical potential, and thereby supersaturation, of solute in the solution leading to crystal nucleation and growth. Despite the extensive use of the antisolvent method in the crystallization of various organic and inorganic crystals, the governing mechanism of the antisolvent in activating this process is not fully understood. Liquid–liquid equilibria for saturated aqueous solution of glycerol+1-butanol+water+sodium chloride at 303.15K, 323.15K and of crystalline materials involves the two most important methods: antisolvent and cooling crystallization. Photoluminescent properties of NaCl:Ce3+ phosphor synthesized using antisolvent crystallization. Solubility measurement of a metastable achiral crystal of sodium chlorate in solution growth.
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